李洪基教授在Organic Letters上发表论文
题目:Electron Donor-Acceptor Complex Enabled Cyclization/Sulfonylation Cascade of N-Heterocycles with Thianthrenium Salts
作者: Zhengjun He, Zhi Li, Shuo Lai, and Hongji Li*
单位:Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, School of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China
摘要:We report a visible light-promoted cyclization/sulfonylation cascade of N-heterocycles with thianthrenium salts using DABSO as the SO2 surrogate. This method features excellent functional group tolerance, wide substrate scope and late-stage elaboration of bioactive relevant molecules. Mechanistic investigations reveal that the photoactive electron donor−acceptor (EDA) complexes between thianthrenium salts and DABCO are capable of the generation of aryl radicals which induces the following SO2 insertion by attacking DABSO, thus triggering the key radical cyclization step.
影响因子:5.2
分区情况:一区
链接:https://doi.org/10.1021/acs.orglett.4c02307
(文:李洪基 / 审核:李洪基 / 审校:韩满意 / 终审:韩满意)
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