李洪基教授在Organic Letters上发表论文
题目:Electrochemical Cyclization of oAminyl Azobenzenes: Roles of Aldehydes in N−N Bond Cleavage
作者:Anni Li, Anna Gao, Kangjia Chen, and Hongji Li*
单位:Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; School of Chemistry and Material Science, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China
摘要:Direct functionalization of azobenzenes provides an approach to obtaining valuable molecules in synthetic chemistry. However, an efficient method for the cleavage of the N=N bond of azobenzenes, which is a key process for this transformation, is still lacking. We herein disclose an electrochemical reduction-induced cyclization of azobenzenes with aldehydes via N=N bond cleavage. This electrochemical cyclization of azobenzenes proceeds well in the absence of any transition metals or external chemical oxidants, leading to the formation of N-protected benzimidazoles in moderate to good yields.
影响因子:5.2
分区情况:一区
链接:https://doi.org/10.1021/acs.orglett.4c01828
(文:李洪基 / 审核:李洪基 / 审校:韩满意 / 终审:韩满意)
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