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孟令国教授、王快博士在Organic Letters上发表论文

来源: 发布时间:2024-05-30 10:02:17 浏览次数: 【字体:

题目:Photochemical Mn-Mediated Generation of Azide Radicals for Improvement of Alkene Hydroxyazidation

 

作者:Chen-Xi Xia, Ziyang Li, Ruyi Ye, Zhao-Juan Wu, Yue Ren, Kuai Wang*, and Ling-Guo Meng*

 

单位:Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China

 

摘要:State-of-the-art strategies for alkene-hydroxyazidation, which yield a mixture of β-azido alcohol and β-azido peroxide, must rely on phosphine reagents to improve the chemoselectivity. To overcome the above problems, we present a photochemical hydroxyazidation of alkenes via Mn-mediated ligand-to-metal charge transfer (LMCT) in O2, which activates N3 to •N3 and incorporates O2 to be used as an oxygen source in the hydroxyazidation products. Broad alkene range and step-economy chemistry for the hydroxyazidation transformation were also demonstrated.

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影响因子:5.2

 

分区情况:一区

 

链接:https://pubs.acs.org/doi/10.1021/acs.orglett.4c00911


                     (文、图:王快 / 审核:李洪基 / 审校:韩满意 / 终审:韩满意)

终审:绿色和精准合成化学及应用教育部重点实验室
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